TN TRB Syllabus 2022: Syllabus for English, Mathematics, Physics, Chemistry, Botany, History, General Knowledge

TN TRB stands for Tamil Nadu Teachers Recruitment Board (TN TRB). This board conducts examinations for the selection of candidates for the recruitment of Post Graduate Assistants. The board has already released the official syllabus so that candidates can prepare accordingly. The syllabus of TN TRB 2022 focuses on determining the intelligence and subject knowledge of  candidates. It is important for an aspirant to know the TN TRB Syllabus 2022 to make a good preparation strategy for the examination. Complete TN TRB Syllabus 2022 is provided in this article.

TN TRB Syllabus 2022 Key Highlights

The subject-wise syllabus for the Tamil Nadu Teachers Recruitment Board (TN TRB) is given below.

TN TRB English Syllabus 2022

Unit-I – MODERN LITERATURE (1400-1600)

Poetry

  • For Detailed Study
    • Chaucer : Prologue to the Canterbury Tales
    • Spenser : Faerie Queene – Book-I
  • For Non-detailed Study
    • Spenser : Prothalamion and Epithalamion
    • Wyatt, Surrey: Selections in Peacock’s English verse, Vol-I
    • Ballads : Peacock – Vol-II

Prose

  • For Detailed Study
    • Bacon – Essays – Of Truth, Of Adversity, Of Studies, Of Revenge, Of Ambition, Of Friendship
    • Sidney : Apologie For Poetrie
  • For Non-detailed Study
    • The Bible : The Book of Job.

Drama

  • For Detailed Study Marlowe : Dr. Faustus
  • For Non-Detailed Study Kyd : The Spanish Tragedy Ben Jonson : The Alchemis

Unit-II – MODERN LITERATURE (1600-1798)

Poetry

  • For Detailed study Donne : Canonisation, The Ecstasie Milton : Paradise Lost, Book-IX Pope : The Rape of the Lock.
  • For Non-detailed Study Milton : Samson Agonistes Gray, Collins & Blake: Peacock’s English Verse – Vol-III Herbert : 1. Affliction 2. The Pulley Marvell : To His Coy Mistress

Prose

  • For Detailed Study Johnson : Life of Milton 2
  • For Non-Detailed Study Bunyan : The Pilgrim’s Progress Fielding : Tom Jones

Drama

  • For Detailed Study Dryden : All for Love Sheridan : The School for Scandal
  • For Non-detailed Study : Congreve : The way of the World Goldsmith : She stoops to conquer

Unit-III – MODERN LITERATURE (1798 – 1832)

Peotry

  • For Detailed Study Wordsworth : Immortality Ode, Tintern Abbey Coleridge : Ode to Dejection, Kubla Khan Keats : Ode on a Grecian Urn, Ode to Autumn. Shelley : Ode to the West Wind
  • For Non-Detailed Study Wordsworth : Prelude – Book-I Shelley : Adonais

Prose

  • For Detailed Study Lamb : Essays of Elia Christ’s Hospital, The South Sea House, Dream children, New Year’s Eve Hazlitt : My First Acquaintance with Poets.
  • For Non-Detailed Study Shelley : A Defence of Poetry Wordsworth : Preface to the Lyrical Ballads (1850) Jane Austen : Emma Emily Bronte: Wuthering Heights

Unit-IV – MODERN LITERATURE (1832 to the present day)

Poetry

  • For Detailed Study: Arnold : Dover Beach, The Scholar Gypsy Browning : Andrea Del Sarto Tennyson : Morte D’ Arthur W.B.Yeats : Byzantium Eliot : The Waste land
  • For Non-Detailed Study: Hopkins : The Wreck of the Deutschland The selections from (i) Owen (ii) W.H.Auden (iii) Stephen Spender in the Faber Book of Modern Verse.

Prose

  • For Detailed Study: Carlyle : The Hero as a Man of Letters (from “On Heroes and Hero Worship”) Mathew Arnold: The Study of Poetry T.S.Eliot : Tradition and Individual Talent
  • For Non-detailed Study: Dickens : Great Expectations George Elliot : Middle March Hardy : Jude the Obscure Virginia Woolf : To the Light House Graham Greene : The Power and the Glory

Unit-V – SHAKESPEARE

Drama

  • For Detailed Study

Macbeth, The Tempest

  • For Non-Detailed Study

Henry–IV Part-I: Measure for Measure Antony and Cleopatra

A general knowledge of the other plays, poems and sonnets of Shakespeare is expected of the candidates

Unit-VI AMERICAN LITERATURE

Poetry

  • Detailed study

Walt Whitman : Out of the Cradle Endlessly Rocking

Emily Dickinson : Because I could not Stop for Death

Robert Frost : Mending Wall, Birches, West Running Brook.

Sylvia Plath : Daddy

  • Non-Detailed Study

Walt Whitman : Passage to India

E.E.Cummings : The Cambridge Ladies

Hart Crane : Poem: To Brooklyn Bridge.

Fiction

  • Mark Twain : The Adventures of Huckleberry Finn

Melville : Moby Dick

Hemingway : The Old Man and the Sea

Prose

  • Detailed study

Emerson : The American Scholar 4

Faulkner : Nobel Prize Acceptance Speech.

  • Non-Detailed Study

Thoreau : Walden James

Thurcer : The Owl in the Attic

Drama

  • Detailed study

Eugene O’ Neil : The Hairy Ape

Arthur Miller : The Death of a Salesman

  • Non-Detailed Study

Tennesse Williams : A Street Car named Desire

Edward Albee : Who’s Afraid of Virginia Woolf?

Unit-VII INDIAN WRITING IN ENGLISH

Poetry

  • Detailed Study: Tagore : Gitanjali Aurobindo : Thought the Paraclete
  • Non-Detailed Study: Poems of Sarojini Naidu and Toru Dutt from the Golden Treasury of Indian Poetry. Poems of A.K.Ramanujam, R. Parthasarathy, Kamala Das and Nissim Ezekiel from “Ten Twentieth Century Indian Poets” ed. R.Parthasarathy.

Fiction

  • Mulk Raj Anand : Coolie Raja Rao : Kantapura R.K. Narayan : The English Teacher Kamala Markandaya: A Handful of Rice.

Prose

  • Detailed Study: Ananda Commarasamy Aurobindo:The Dance of Shiva (The Title Essay)
  • Non-Detailed Study: Nehru : An Autobiography

Drama

  • Detailed Study: Tagore : Muktha Dhara Girish Karnad : Tughlaq
  • Non-Detailed Study: Gurucharan Das : Larine Sahib

Commonwealth Literature

Poetry

  • Non-Detailed Study: 5 E.J. Pratt : The Dying Eagle Judith Wright : Fire in the Murdering Hut, The Cedars Wole Soyinka : The Telephone conversation Abioseh Nicoll : The Meaning of Africa A.D.Hope : Australia

Drama

  • Detailed Study Wole Soyinka : The Lion and the Jewel
  • Non–Detailed Study Douglas Stewart : Ned Kelly

Prose

  • Chinua Achebe : The Novelist as Teacher

Fiction

  • Chinua Achebe : Things Fall Apart
  • Alan Paten : Cry, the Beloved Country

Unit-VIII — APPROACHES TO LITERATURE

  1. Modern Drama
  2. Modern Fiction
  3. Literary Movements
  4. Literary Criticism and Theory
  5. Feminism
  6. Teaching of English in India
  7. Journalism and Creative Writing in English
  8. Post – Modernism

Unit-IX – HISTORY OF THE ENGLISH LANGUAGE

  1. Origin of Language
  2. Place of English in the Indo-European family
  3. General Characteristics of Old and Middle English
  4. The rise and growth of Modern English
  5. Growth of Vocabulary Greek, Latin, French, Italian, Scandinavian and other foreign influences – Word Formation.
  6. Change of Meaning
  7. The Makers of English, The Bible, Spenserm, Shakespeare, Milton and Dr.Johnson.
  8. American English
  9. Indian English

10.Characteristics of Modern English

11.Spelling Reform

12.The English Lexicon

TN TRB Mathematics Syllabus 2022

  • Unit-I – Algebra Groups – Examples – Cyclic Groups- Permulation Groups – Lagrange’s theorem- Cosets – Normal groups – Homomorphism – Theorems – Cayley’s theorem – Cauchy’s Theorem – Sylow’s theorem – Finitely Generated Abelian Groups – Rings- Euclidian Rings- Polynomial Rings- U.F.D. – Quotient – Fields of integral domains- Ideals- Maximal ideals – Vector Spaces – Linear independence and Bases – Dual spaces – Inner product spaces – Linear transformation – rank – Characteristic roots of matrices – Cayley Hamilton Theorem – Canonical form under equivalence – Fields – Characteristics of a field – Algebraic extensions – Roots of Polynomials – Splitting fields – Simple extensions – Elements of Galois theory- Finite fields.
  • Unit-II – Real Analysis Cardinal numbers – Countable and uncountable cordinals – Cantor’s diagonal process – Properties of real numbers – Order – Completeness of R-Lub property in R-Cauchy sequence – Maximum and minimum limits of sequences – Topology of R.Heine Borel – Bolzano Weierstrass – Compact if and only if closed and bounded – Connected subset of R-Lindelof’s covering theorem – Continuous functions in relation to compact subsets and connected subsets- Uniformly continuous function – Derivatives – Left and right derivatives – Mean value theorem – Rolle’s theorem- Taylor’s theorem- L’ Hospital’s Rule – Riemann integral – Fundamental theorem of Calculus –Lebesgue measure and Lebesque integral on R’Lchesque integral of Bounded Measurable function – other sets of finite measure – Comparison of Riemann and Lebesque integrals – Monotone convergence theorem – Repeated integrals.
  • Unit-III – Fourier series and Fourier Integrals Integration of Fourier series – Fejer’s theorem on (C.1) summability at a point – Fejer’s-Lebsque theorem on (C.1) summability almost everywhere – Riesz-Fisher theorem – Bessel’s inequality and Parseval’s theorem – Properties of Fourier co-efficients – Fourier transform in L (-D, D) – Fourier Integral theorem – Convolution theorem for Fourier transforms and Poisson summation formula.
  • Unit-IV – Differential Geometry Curves in spaces – Serret-Frenet formulas – Locus of centers of curvature – Spherical curvature – Intrinsic equation – Helices – Spherical indicatrix surfaces – Envelope – Edge of regression – Developable surfaces associated to a curve – first and second fundamental forms – lines of curvature – Meusnieu’s theorem – Gaussian curvature – Euler’s theorem – Duplin’s Indicatrix – Surface of revolution conjugate systems – Asymptritic lines – Isolmetric lines – Geodesics.
  • Unit-V – Operations Research Linear programming – Simplex Computational procedure – Geometric interpretation of the simplex procedure – The revised simplex method – Duality problems – Degeneracy procedure – Peturbation techniques – integer programming – Transportation problem – Non-linear programming – The convex programming problem – Dyamic programming – Approximation in function space, successive approximations – Game theory – The maximum and minimum principle – Fundamental theory of games – queuing theory / single server and multi server models (M/G/I), (G/M/I), (G/G1/I) models, Erlang service distributions cost Model and optimization – Mathematical theory of inventory control – Feed back control in inventory management – Optional inventory policies in deterministic models – Storage models – Damtype models – Dams with discrete input and continuous output – Replacement theory – Deterministic Stochostic cases – Models for unbounded horizons and uncertain case – Markovian decision models in replacement theory – Reliability – Failure rates – System reliability – Reliability of growth models – Net 2 work analysis – Directed net work – Max flowmin cut theorem – CPM-PERT – Probabilistic condition and decisional network analysis.
  • Unit-VI – Functional Analysis Banach Spaces – Definition and example – continuous linear transformations – Banach theorem – Natural embedding of X in X – Open mapping and closed graph theorem – Properties of conjugate of an operator – Hilbert spaces – Orthonormal bases – Conjugate space H – Adjoint of an operator – Projectionsl 2 as a Hilbert space – lp space – Holders and Minkowski inequalities – Matrices – Basic operations of matrices – Determinant of a matrix – Determinant and spectrum of an operator – Spectral theorem for operators on a finite dimensional Hilbert space – Regular and singular elements in a Banach Algebra – Topological divisor of zero – Spectrum of an element in a Branch algebra – the formula for the spectral radius radical and semi simplicity.
  • Unit-VII – Complex Analysis Introduction to the concept of analytic function – limits and continuity – analytic functions – Polynomials and rational functions elementary theory of power series – Maclaurin’s series – uniform convergence power series and Abel’s limit theorem – Analytic functions as mapping – conformality arcs and closed curves – Analytical functions in regions – Conformal mapping – Linear transformations – the linear group, the cross ratio and symmetry – Complex integration – Fundamental theorems – line integrals – rectifiable arcs – line integrals as functions of arcs – Cauchy’s theorem for a rectangle, Cauchy’s theorem in a Circular disc, Cauchy’s integal formula – The index of a point with respect to a closed curve, the integral formula – higher derivatives – Local properties of Analytic functions and removable singularitiesTaylor’s theorem – Zeros and Poles – the local mapping and the maximum modulus Principle.
  • Unit-VIII – Differential Equations Linear differential equation – constant co-efficients – Existence of solutions – Wrongskian – independence of solutions – Initial value problems for second order equations – Integration in series – Bessel’s equation – Legendre and Hermite Polynomials – elementary properties – Total differential equations – first order partial differential equation – Charpits method.
  • Unit-IX – Statistics – I Statistical Method – Concepts of Statistical population and random sample – Collections and presentation of data – Measures of location and dispersion – Moments and shepherd correction – cumulate – Measures of skewness and Kurtosis – Curve fitting by least squares – Regression – Correlation and correlation ratio – rank correlation – Partial correlation – Multiple correlation coefficient – Probability Discrete – sample space, events – their union – intersection etc. – Probability classical relative frequency and axiomatic approaches – Probability in continuous probability space – conditional probability and independence – Basic laws of probability of combination of events – Baye’s theorem – probability functions – Probability density functions – Distribution function – Mathematical Expectations – Marginal and conditional distribution – Conditional expectations.
  • Unit-X – Statistics-II Probability distributions – Binomial, Poisson, Normal, Gama, Beta, Cauchy, Multinomial Hypergeometric, Negative Binomial – Chehychev’s lemma (weak) law of large numbers – Central limit theorem for independent identical variates, Standard Errors – sampling distributions of t, F and Chi square – and their uses in tests of significance – Large sample tests for mean and proportions – Sample surveys – Sampling frame – sampling with equal probability with or without replacement – stratified sampling – Brief study of two stage systematic and cluster sampling methods – regression and ratio estimates – Design of experiments, principles of experimentation – Analysis of variance – Completely randomized block and latin square designs

TN TRB Physics Syllabus 2022

  • UNIT- I – Vector

Fields General expression for gradient, divergence curl and Laplace operators in orthogonal curvilinear Co-ordinates and their explicit form in Cartesion spherical-co-ordinates, Stokes theorem and Gauss theorem.

  • Matrix theory Algebraic operation – Rank of a matrix. Eigen values and Eigen vectors – characteristic equation – Cayely Hamilton theorem – Diagonalisation and Diagonalizability of unitary orthogonal. Hermitian and symmetric matrices.
  • Special functions Legendre, Hermite and Lagune equation basic properties – Gamma and Beta functions.
  • UNIT-II – Probability and Theory of errors

Basic concept of probability distribution – Exclusive events and addition – Compound events and products – Binomial – Poisson and Guassian distribution – Normal distribution of error – Standard error – Principle of least squares – Application of solution of linear equation – Curve fitting.

Group theory Definition – Sub-groups – Homomorphism and isomorphism – Group representations – Irreducible representation – Unitary representation.

  • UNIT – III – Classical mechanics

Generalised co-ordinates – D’Alembert’s principle, Lagrangian equation of motion – Hamiltonian equation – Conservative and non-conservative systems – Hamilton equation, cyclic variables, principle of least action – Theory of small oscillations – Normal co-ordinates and normal modes – Linear Triatomi molecule – Rigid bodies -Moments and products of inertia-Euler’s angle – Euler’s equation of motionSymmetric top.

  • UNIT-IV – Statistical Mechanics

Maxwell Boltzmann statistics Maxwellian distribution of velocities – Mean – root mean square and most probable velocities Bose-Einstein statistics – Distribution function – Phonon gas – Black body radiation – Fermy-Dirac statistics – Distribution function – Electron gas – Pauli paramagnetism – Thermionic emission – Elementary idea of phase transition – Properties of liquid Helium – phase space, Liouville’s theorem – statistical equation – micro canonical ensembles – Equation of statethermodynamic functions of an ideal gas equipartition of energy.

  • UNIT-V – Electromagnetic theory

Coulomb law – Gauss law – Poisson’s equation – Laplace equation and solution to boundry value problem – Electrostatics of dielectric media – Molecular polarisability and its application – Vector – Scalar potential – B and H in a magnetic material – Maxwell’s equations and their significance – Poynting theorem – Radiation of oscillating dipole.

  • Relativistic Mechanics Basic ideas – Lorentz transformation. Time dilation and Lorentz contraction -Velocity addition law – Momentum and energy in relativistic Mechanics – Centre of mass system for two relativistic particles.
  • UNIT-VI – Spectroscopy

Rotation spectra – Vibration spectra – Rotation vibration spectra of diatomic and linear molecules – Raman Spectra – experimental techniques and classical theory of Raman Scattering – Electronic state of diatomic molecules – Frank–Condon principle – Hund’s coupling scheme – Evaluation of molecular constant from vibrational spectra data. Interaction between nuclear spin and magnetic field – Nuclear resonance-Chemical shift-Dipole-Dipole interaction-Spin lattice interaction.

  • UNIT-VII – Solid State Physics

Energy levels and density of states in one, two and three dimensions – Electrical and Thermal conductivities – Wiedmann-Franz law. Energy bands in solids – Transport phenomena in semiconductors operational functions of a junction diode-Schottky diode – Bloch theorem – Krong-Penny mudel – Brillouin zones – Wave equation of an electron in a periodic potential.

  • Thermal Properties of solids Laws of Thermodynamics – Maxwell’s relations and their applications – Phase transitions – Production and measurement of low temperatures –Einstein and Debye theory of specific heats of solids.
  • Magnetic properties of materials Langevin’s theory of dia-para-magnetism – Quantum theory of para – magnetism – Ferro – magnetism – Ferri – magnetism – superconductivity – Meissner effect – Thermodynamics of superconducting materials – London equation – B.C.S. theory – Josephson’s effect.
  • UNIT-VIII – Quantum mechanics

Schrodinger’s wave equation – Free particle – Particle in a potential well and barrier penetration – The probability interpretation – Expectation value – Eigen functions and eigen values – Stationery states – Wave packet – Uncertainty principle – Linear Harmonic oscillator – angular momentum and addition of angular momenta. Peturbation theory – Transition probability – Constant and harmonic perturbation – Scattering theory – Differential and total scattering cross section – Born approximation – Partial wave analysis and phase shift analysis – Relativistic wave equations – Klein – Gordon equations – Dirac equation and its free particle solution.

  • UNIT-IX – Nuclear Physics

Binding energy – Semi empirical mass formula – Stability of nuclei – Nuclear forces – Ground state of deuteron – Alpha decay – B decay – Fermi’s theory – Selection rules – Liquid drop model – Nuclear fission – Shell model – Collective models. Nuclear Instrumentation Cyclotron – Synchro cyclotron – Proton synchrotron – Detectors – G.M.Counter – Scintillation Counter – Bubble chamber – Nuclear reactors – Neutron cross section – Fission product – Energy release – Chain reaction – Multiplication factor – Moderator – Natural Uranium – Diffusion equation.

  • Unit X – Electronics (Digital electronics)

Binary – Decimal – Octal and Hexadecimal numbers – 8421 Excess–3 – Gray Codes – Logic gates – Laws Boolean algebra – Half and full adders – Subtractors – RS, RST, JK and M/S Flip-flops – Ripple counter – Decade counter –Up-down counter – Serial and parallel registers.

Operational amplifier Differential amplifier – Parameters – Applications – Analog integration and differentiation – Analog computation – Comparators – Sample and hold circuits – Oscillator – Hartley-Colpitt-Phase Shift – Wien’s bridge oscillators – Astable mono -Bistable multivibrators – Clipping and clamping circuits.

Microwave Physics Microwave generation – Klystron – Magnetron – Travelling wave tubes – Microwave in rectangular and cylindrical wave guides – Characteristics of Antennas – Short dipole radiation – Antenna gain – Directivity – Radiation resistance – Radiation intensity.

Microprocessor

Evolution of Microprocessors – Organisation of micro-computers- Preliminary concepts – Basic concepts of programming – Architecture – Address – Data and control buses – Memory decoding – Memory mapped I/O and I/O mapped I/O. Machine and instruction cycles – Addressing modes – Use of arithmetic logical data – Transfer stack and I/O instructions – Instruction set and assembly programming of 8085 microprocessor – Fetch – Execute – overlap – Instruction cycles – Instruction forward – Memories – RAM-PROMS, EPROMSEEPROMS – Static and Dynamic RAM.

TN TRB Chemistry Syllabus 2022

  • Unit-I

Periodic properties – Atomic radius – ionic radius, ionization potential, electron affinity and electronegativity – Their significance in chemical bonding.

VB theory, MO theory – applications – Comparision of VB and MO theories – VSEPR theory – Bond order – Bond energy – Bond length Bond polarity – Partial ionic character of bonds – The concept of multi-centre bond – Electron deficient compounds – Hydrogen bond – Its influences.

Non aqueous solvents – A general study of typical reactions in non aquieous media – comparison with reactions in aqueous media.

Solid state chemistry – Ionic bonding – Lattice energy – Born equation – Born Haber cycle – Radius ratio rule – Born Meyer equation – Kapustinski’s Modification – energetics of the dissolution of ionic compounds in polar solvents – different types of electostatic interactions.

Structural aspects of solids – Fourier synthesis and analysis structure factors – scattering factors – Spinels and Inverse spinels – defects in stoinchiometric and Non stoichiometric crystals.

Electrical properties of solids – Band theory semi conductors – Junction devices – Super conductivity – Ionic conductivity – Optical properties of solids – Lasers and phosphors – Photovoltaic effect – solar energy.

Magnetic properties of solids – Different types – dia, para, ferro, antiferro and ferri Magnetism – Magnetic hysteresis.

  • Unit – II

Co-ordination chemistry – Methods of preparation of complexes – isomerism in complexes – applications of complex formation in analytical chemistry – complexes and their stability chelate effect Stability constants – Their determination – complexes of Metals in different oxidation states and their stability.

Optical activity and concept of chirality – Different kinds of opticalloy active compounds – configuration – Foscher, sawhorse and Newman projections – Absolute configuration R and S Notations – Methods with more than one chiral center – Asymmetric synthesis – optical purity

Geometrical isomerism resulting from double bonds – The E.Z. system of nemenclature – Geometrical isomerism of monocyclic compounds and fused ring systems – Sterospecific and stereo selective reactions with examples.

Confermational analysis – conformation and reactivity in acylic and cyclo – hexane systems – conformation of decalins, cyclohexane and cyclohexanone.

  • Unit – III

Organic reaction mechanisms – General methods of investigating reaction mechanisms – kinetic and non-kinetic methods – different types of reaction intermediates.

Aliphatic nucleophilic substituion SN1, SN2 and SNi reactions – substitution at vinylic and benzylic carbon – stereo chemistry of nucleophilic reaction – solvents and substituent effects – Nucleophilicity Neighboring group participation.

Addition to double and triple bonds – Mechanism Hydration – Hydroboration – Hydroxiylation – epoxidation.

Elimination reactions E1, E2, E1cB Mechanism – Orientation effects in elimination reactions – stereo chemistry of elimination reactors – dehydration of alcohols – dehydro halogenation – cope elemination.

Heterocyclics – synthesis and reactivity of furan, thiophene, pyrrole pyridine, quinoline, isoquinoline, Indole, flavenes, and anthocyanins – skraup synthesis – Fischer indole synthesis.

The chemistry ;of natural products structure elucidations and Biogenesis of the following:

  • Alkaloids : Reticulene, Reserpine, Morphine
  • Terpenoids : Zingiberene, Squalene, Lanosteroal
  • Steroids : Cholesterol, Oestrone, Progresterone
  • Carbohydrates: Maltose, Starch, Cellulose (biogenis not expected)

Structure and functions of biopolymer such as proteins and Nucleic acids – Primary, Secondary and tertiary structures of proteins – Mechanism of Enzyme action – DNA and RNA.

  • Unit – V

Thermodynamic equations of state – closed and open systems – partial molal quantities – chemical potential with temperature and pressure – third law of thermodynamics.

Fugacity – methods of determination – activity and activity co-efficient – standard states for gases, liquids – solids and solutions – mean activity co-efficients of electrolytes.

Maxwell’s distribution of molecular velocities – derivation of expression for average, most probable and rcot mean square velocities – Microstates Macrostates – partial functions – Sackur tetrode equation – statistical approach to the third law of Thermodynamics – Maxwell Boltzmann – Bose Einstein and Fermi

Dirace statistics – Heat capacities of solids – Einstein and Debye Models Low temperature – Negative absolute temperature.

Chemical equilibrium – thermodynamic derivation of equilibrium constant – standard free energy – calculations.

Phase equilibrium – thermodynamic derivation of phase rule application of phase rule – three component systems.

Chromotography – column, paper, thinlayer, gas-liquid, High pressure liquid chromatography HPLC principle and applications.

Thermal analysis – different thermal analysis (DTA) – Principle and applications – thermogravimetric analysis (TGA) Principle and application.

Chemical crystallography – Diffraction methods – X ray Neutron, electron diffraction methods. Principle and applications.

Polarimetry – Circular ichroism – Optical Rotatory dispersion (ORD) principle and applications.

  • Unit – VI

Nuclear – chemistry – Nuclear nadii spin and moments – Nuclear structure – Nuclear forces – Nuclear stability – Nuclear modes – Modes of Radioactivity decay. Nuclear isomerisation Nuclear Reaction Energy – Coulomb barrier cross section – excitation function – Radiactive Equiliberia – Types of Neclear reactions – Nuclear fision Nuclear Reactors – Atomic Power Project in India – Radiation hazards – Radiation desimetry – Nuclear fusion – Stellar Energy.

Application of Radioactivity – Tracer Techniques – Neutron – Activation analysis – Isotope Dilution Analysis – Interaction of radiation with matter – Range of alpha and beta particles – Absorption co-efficient,.

Orgnometallic compounds – Metallecences – Arene complexes – Nonaromatie olefins and acetylenes complexes – catalysis by organometallic compounds Wilkinson’s catalyst – Oxoprocess – wecker process – Ziegler – Natta catalysis.

Inorganic photo chemistry – Photochemical reactions of coordination and organ metallic compounds – Properties of excited states – charge transfer photo Oxidation, photo reduction, photo substitution, photo isomerisation – Photo chemical conversion – Solar energy.

  • Unit – VII

Term symbols and term states – Dn – ions energy levels – Diagrams weakfield and strong field and strong field concepts – spin orbit coupling – The Nephelanxetic effect charge transfer spectra – Applications of UV, IR, NMR, BSR and mossbaver spectroscopy techniques in the study of co-ordination chemistry.
Magnetic interactions – Magnetic susceptibilities determination – application in co-ordination chemistry. Application of VB, MO, CF and LF theories in co-ordination chemistry – Group theoretical approach – splitting of d-orbitals – spectro-chemical series – concept of weak and strong fields – Thermodynamic and chemical effect of d-orbitals splitting – Jahn Teller distortion.

Nuclear Magnetic Resonance Spectroscopy – Theory – Study of PMR – chemical shift – Type of shielding – Spin-spin coupling spin decoupling – spplications to simple natural products. 4 Electron spin resonance spectro scopy – paramagnetism – Nuclear hyperfine structure – Hyperfine coupling.

  • Unit VIII

Huckel’s rule and concept of aromaticity – aromaticity of Benzenoid – Nonbenzenoid aromatics. The annulenes – Aromaticity in charged rings and fused ring systems. Aromatic electrophilic substitution – Mechanism and reactivity, Typical reactions to include diazonium coupling – Halognation, sulphonation. Friedal craft alkylation and acylation. Aromatic Nucleophilic substitution – Benzyne mechanism – Examples. Oxidation – Reduction reactions – Mechanisms – selectivity in oxidations and reductions.

Molecular rearrangements – Rearrangements with Carbon to Nitrogen, Carton to Oxygen and Carbon migrations. Curtivs, Lossen, Schmitts Baeyer – Villiger, Pinacol – Pinacolene, Benzoil – Benzilicacid, Benzidine, Favorski and fries rearrangements – sigmatropic rearragements – claisen and cope. Pericyclic reactions, selection rules – orbital symmetry – Electrocyclic reactions – cycle additions sigmatropic reactions.

Modern synthetic reactions – Diels alder reaction witting reactions – stork Enamine reactions – Mannich reactions, Birch reductions.

  • Unit IX

Theories of reaction rates – simple collision theory – absolute reaction rate theory (ARRT) – Reaction co-ordinate – Potential energy surfaces. Hammett – Taft equation – Hammett acidity function – Acid base catalysis Bronsted relation Enzyme catalysis – Michaelis Menton Law – influence of PH and temperature. Surface phenomenon – Heterogeneous catalysis – Absorption isotherms. Electrolytic conductance – applications – solubility product – Interionic attraction theory – Debye – Huckel – Onsager equation – equivalent conductivity of electro lytes.

Electro potentials – Electrochemical cells – electrode – electrolyte interface – electrical double layer electro capillary phenomena – electro kinetic Phenomena – Membrane potential – Polarisation – over potential – Polarography – concentration polarization – electro chemical polarization – sutler – Volmer equation.

  • Unit X

Theory and applications of the following spectroscopic methods; electonics spectra-UV-Visible spectra – IR spectra – Raman spectra – Laser – Raman spectra – NMR – WCR- ESR Spectra – Mossbaver spectro scopy – photoelectron spectro scopy – Polymerisation reactions – Mechanism – sterochemical aspects. Types of polymers – organic and inorganic polymers – preparation – properties – structure – polystyrene – Polyvinylchloride – Polyesters – Nylon – Phenol resin – amino resins – epoxy resins. Phosphonitrilic compounds – silicons – Borazines applications of polymers.

TN TRB Botany Syllabus 2022

  • Unit I : Viruses, Bacteria, Thallaophytes and Lichens.
  • Unit II : Plant Pathology and Microbiology
  • Unit III : Bryophytes, Pteridophytes and Gymnosperms
  • Unit IV : Morphology, Taxonomy and Economic Botany
  • Unit V : Cell Biology and Genetics
  • Unit VI : Anatomy and Embryology
  • Unit VII : Plant Physiology and Bio-Chemistry
  • Unit VIII : Plant Breeding and Bio-Technology
  • Unit IX : Ecology and Phytogeography
  • Unit X : Palaeo Botany and General Principles

TN TRB History Syllabus 2022

  • Unit -1

Sources of Indian – History – Geography of Indian- Harappan civilization – vedic age – Jainism and Buddhism – mauryas – Chandra gupta- Ashoka – mayuran administration – kanishka-Guptas

– Sumudra Gupta –Chandra gupta II – classical age – Harshavarthana.

  • Unit –II

Arab conquest of sindh and muslim invasions slave dynasty – Alavuddin khilji – ThuglaqsSociety – Religion and culture under the Vijayanger rule .

  • Unit –III

Mughals- Babar to Aurangzeb – Shershah Suri- Administration – Society, Religion and Culture under the Mughals – Shivaji – Maratha administration

  • Unit – IV

Foundation of British rule in India – Robert Clive – Warren Hastings – Corn Wallis, Wellesley, Hastings, William Bentick – Dalhousie

  • Unit-V

Great Mutiny 1857 – Social and religious reform movements in India in the nineteenth century – Indian – National Movement – Constitutional development in India from 1858 to 1947.

  • Unit – VI

Integration of Indian States – Republican Constitution of India, Gandhian and Nehru Eras – India’s role in world affairs

  • Unit – VII

Sources of the History of Tamilnadu – Sangam age and its culture – Pallava dynasty – Social, Economic, Religious and Cultural developments under Pallvas – Imperial Cholas and their

administration, Social Life, religion and culture.

  • Unit – VIII

Later Pandyas and the Muslim invasions in Tamil Nadu Thirumalainaikker – Later Polygar rebellion – Tamil Nadu and Freedom struggle – Social reform movements in Tamil Nadu – Political social and economic developments in Tamil Nadu since 1947.

  • Unit – IX

Geographical discoveries, Renaissance and Reformation Age of Enlightened depots – Industrial and Agrarian revolutions – French revolution – Napoleon – Congress of Vienna

  • Unit – X

Unification of Italy and Germany – Russian revolution – First World War and Peace Treaties – League of Nations, Rise of Dictatorships – Hitler, Mussolini and Kamal Paksha – II World War – U.N.O. and Cold War.

TN TRB General Knowledge Syllabus 2022

  • Unit – I Indian History History of India – Vedic period 1526 AD to 1947 – Free India – Modern India
  • Unit-II Indian Constitution Origin of Indian Constitution – Salient and special features – Fundamental rights – Legislature – Judiciary – Executive – Adult franchise – Human rights
  • Unit-III History of Tamil Nadu Ancient period – Sangam age – Chera, Chola, Pandias – Economical, political, social conditions – Literature – Architecture – Fine arts – Geography of Tamil Nadu – Natural boundaries – Resources – Rivers and places.
  • Unit-IV Personalities Books and authors – Discoveries
  • Unit-V Sports & Games (confined to India)
  • Unit-VI Abbreviations
  • Unit-VII Every Day Science
  • Unit-VIII Current Affairs

Note: The candidates may check the detailed syllabus of the rest of the subjects through the official website of the board.

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